Detail publikačního výsledku
alfa-olefin polymerization initiated by nickel catalysts:A mechanistic investigations by means of kinetic and UV-visible spectroscopy.
Merna, J., Deffieux, A., Cramail, H.
Original Title
alfa-olefin polymerization initiated by nickel catalysts:A mechanistic investigations by means of kinetic and UV-visible spectroscopy.
English Title
alfa-olefin polymerization initiated by nickel catalysts:A mechanistic investigations by means of kinetic and UV-visible spectroscopy.
Type
Paper in proceedings (conference paper)
Original Abstract
Kinetic study of pent-1-ene and 4-methylpent-1ene polymerization initiated by nickel diimine catalyst was performed to examine the effect of monomer structure on the polymerization rate and the polyolefin microstructure, and correlated with chain-walking mechanism. Active species formation was investigated by UV-VIS spectroscopy.
English abstract
Kinetic study of pent-1-ene and 4-methylpent-1ene polymerization initiated by nickel diimine catalyst was performed to examine the effect of monomer structure on the polymerization rate and the polyolefin microstructure, and correlated with chain-walking mechanism. Active species formation was investigated by UV-VIS spectroscopy.
Keywords
polyolefin, nickel catalyst, kinetics, UV-VIS, mechanism
Key words in English
polyolefin, nickel catalyst, kinetics, UV-VIS, mechanism
Authors
Merna, J., Deffieux, A., Cramail, H.
Released
06.07.2004
Location
Paris
Book
CD-ROM+www.e-polymers..org/paris
Pages from
CD
Pages count
2
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