Detail publikačního výsledku
Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives
CIGÁNEK, M.; HEINRICHOVÁ, P.; KUČERÍK, J.; KRAJČOVIČ, J.
Original Title
Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives
English Title
Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives
Type
Abstract
Original Abstract
The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.
English abstract
The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.
Keywords
diketopyrrolopyrrole; asymmetrical alkylation; adamantyl
Key words in English
diketopyrrolopyrrole; asymmetrical alkylation; adamantyl
Authors
CIGÁNEK, M.; HEINRICHOVÁ, P.; KUČERÍK, J.; KRAJČOVIČ, J.
Released
21.11.2019
Publisher
Vysoké učení technické v Brně, Fakulta chemická
Location
Brno
ISBN
978-80-214-5807-9
Book
Studentská odborná konference Chemie je život 2019
Edition
první
Pages from
72
Pages to
72
Pages count
1
Full text in the Digital Library
BibTex
@misc{BUT160834,
author="Martin {Cigánek} and Patricie {Heinrichová} and Jiří {Kučerík} and Jozef {Krajčovič}",
title="Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives",
booktitle="Studentská odborná konference Chemie je život 2019",
year="2019",
series="první",
pages="72--72",
publisher="Vysoké učení technické v Brně, Fakulta chemická",
address="Brno",
isbn="978-80-214-5807-9",
note="Abstract"
}