Detail publikačního výsledku

Solid‐state grafting of maleic anhydride onto polypropylene: The influence of morphology of polypropylene on heterogeneous reaction

KUČERA, F.; PETRUŠ, J.; BÁLKOVÁ, R.; JANČÁŘ, J.

Original Title

Solid‐state grafting of maleic anhydride onto polypropylene: The influence of morphology of polypropylene on heterogeneous reaction

English Title

Solid‐state grafting of maleic anhydride onto polypropylene: The influence of morphology of polypropylene on heterogeneous reaction

Type

WoS Article

Original Abstract

Polypropylene (PP) was modified with maleic anhydride (MAH) via heterogeneous solid-state radical grafting performed in a fluidized polymerization reactor. The effect of PP morphology and different concentration of initiator (dibenzoyl peroxide, DBP) on the course of the reaction and grafting efficiency was evaluated with using infrared spectroscopy, scanning electron microscopy (SEM) and particle surface analysis (BET method). With respect to obtained results, the reaction course can be strongly affected by the reaction conditions and PP morphology. Unlike the reactive modification in melt, heterogeneous reaction exhibits lower extent of beta-scission albeit the reaction conversion is lower. Solid-state grafting can be used as an alternative method for the surface modification of nonpolar surfaces with polar monomers under mild conditions.

English abstract

Polypropylene (PP) was modified with maleic anhydride (MAH) via heterogeneous solid-state radical grafting performed in a fluidized polymerization reactor. The effect of PP morphology and different concentration of initiator (dibenzoyl peroxide, DBP) on the course of the reaction and grafting efficiency was evaluated with using infrared spectroscopy, scanning electron microscopy (SEM) and particle surface analysis (BET method). With respect to obtained results, the reaction course can be strongly affected by the reaction conditions and PP morphology. Unlike the reactive modification in melt, heterogeneous reaction exhibits lower extent of beta-scission albeit the reaction conversion is lower. Solid-state grafting can be used as an alternative method for the surface modification of nonpolar surfaces with polar monomers under mild conditions.

Keywords

maleic anhydride; morphology; polypropylene; postpolymerization modification; solid-state reaction

Key words in English

maleic anhydride; morphology; polypropylene; postpolymerization modification; solid-state reaction

Authors

KUČERA, F.; PETRUŠ, J.; BÁLKOVÁ, R.; JANČÁŘ, J.

RIV year

2021

Released

09.03.2020

Publisher

John Wiley & Sons, Inc.

Location

USA

ISBN

0032-3888

Periodical

POLYMER ENGINEERING AND SCIENCE

Volume

60

Number

5

State

United States of America

Pages from

1076

Pages to

1082

Pages count

7

URL

https://onlinelibrary.wiley.com/doi/full/10.1002/pen.25363

Full text in the Digital Library

http://hdl.handle.net/

BibTex

@article{BUT166050,
  author="František {Kučera} and Josef {Petruš} and Radka {Bálková} and Josef {Jančář}",
  title="Solid‐state grafting of maleic anhydride onto polypropylene: The influence of morphology of polypropylene on heterogeneous reaction",
  journal="POLYMER ENGINEERING AND SCIENCE",
  year="2020",
  volume="60",
  number="5",
  pages="1076--1082",
  doi="10.1002/pen.25363",
  issn="0032-3888",
  url="https://onlinelibrary.wiley.com/doi/full/10.1002/pen.25363"
}