Detail publikačního výsledku

What can kinetics learn from rational thermodynamics

PEKAŘ, M.

Original Title

What can kinetics learn from rational thermodynamics

English Title

What can kinetics learn from rational thermodynamics

Type

Peer-reviewed article not indexed in WoS or Scopus

Original Abstract

Within the framework of rational thermody-namics an interesting approach to chemical kinetics was developed. Using this approach, non-traditional rate equations can be derived with new insights on the relations between mechanism, i.e. set of elementary steps, and kinetics. This contribution presents illustrative exam-ples of this approach and discusses its consequences for mechanistic and kinetic interpretation of kinetic experiments and their design.

English abstract

Within the framework of rational thermody-namics an interesting approach to chemical kinetics was developed. Using this approach, non-traditional rate equations can be derived with new insights on the relations between mechanism, i.e. set of elementary steps, and kinetics. This contribution presents illustrative exam-ples of this approach and discusses its consequences for mechanistic and kinetic interpretation of kinetic experiments and their design.

Keywords

Kinetics, Modelling, Rate Equation, Reaction Engineering, Reaction Mechanism, Thermodynamics Process

Key words in English

Kinetics, Modelling, Rate Equation, Reaction Engineering, Reaction Mechanism, Thermodynamics Process

Authors

PEKAŘ, M.

Released

01.01.2004

ISBN

0009-2509

Periodical

CHEMICAL ENGINEERING SCIENCE

Volume

59

Number

19

State

United States of America

Pages from

4103

Pages count

10

Full text in the Digital Library

http://hdl.handle.net/

BibTex

@article{BUT42130,
  author="Miloslav {Pekař}",
  title="What can kinetics learn from rational thermodynamics",
  journal="CHEMICAL ENGINEERING SCIENCE",
  year="2004",
  volume="59",
  number="19",
  pages="10",
  issn="0009-2509"
}