Publication result detail
Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium
Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.
Original Title
Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium
English Title
Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium
Type
Peer-reviewed article not indexed in WoS or Scopus
Original Abstract
Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.
English abstract
Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.
Keywords
Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins
Key words in English
Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins
Authors
Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.
Released
01.02.2005
Publisher
Elsevier
ISBN
0014-3057
Periodical
EUROPEAN POLYMER JOURNAL
Volume
2005
Number
41
State
United Kingdom of Great Britain and Northern Ireland
Pages from
303
Pages to
312
Pages count
9
BibTex
@article{BUT46276,
author="Jan {Merna} and Jaroslav {Cihlář} and Miloslav {Kučera} and Alain {Deffieux} and Henri {Cramail}",
title="Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium",
journal="EUROPEAN POLYMER JOURNAL",
year="2005",
volume="2005",
number="41",
pages="303--312",
issn="0014-3057"
}