Detail publikačního výsledku
Kinetics of Sorption of Metal Ions on Lignitic Humic Acids
KLUČÁKOVÁ, M.
Original Title
Kinetics of Sorption of Metal Ions on Lignitic Humic Acids
English Title
Kinetics of Sorption of Metal Ions on Lignitic Humic Acids
Type
Peer-reviewed article not indexed in WoS or Scopus
Original Abstract
Affinity of humic acids (HA) to heavy metals is well known. Many authors use copper as model metal for study of interaction with HA due to its high complexation ability and affinity to HA. My previous works showed that classical Langmuir isotherm, which is frequently used for mathematical description of equilibrium sorption of metal ions on HA and determination of sorption capacity, is connected with some inaccuracies, because it does not take into account the production of hydrogen ions during reactions of metal ions with acidic functional groups on the surface of humic particles. In view of the fact, that Langmuir isotherm is based on kinetics of sorption process, I develop new model for equilibrium sorption of metal ions on HA including splitting of hydrogen ions in chemical sorption on acidic groups. The model was proved experimentally for sorption of cupric ions. This work deals with kinetics of sorption of cobalt and nickel ions on HA to prove above mentioned new model for metal ions with lower affinity to HA.
English abstract
Affinity of humic acids (HA) to heavy metals is well known. Many authors use copper as model metal for study of interaction with HA due to its high complexation ability and affinity to HA. My previous works showed that classical Langmuir isotherm, which is frequently used for mathematical description of equilibrium sorption of metal ions on HA and determination of sorption capacity, is connected with some inaccuracies, because it does not take into account the production of hydrogen ions during reactions of metal ions with acidic functional groups on the surface of humic particles. In view of the fact, that Langmuir isotherm is based on kinetics of sorption process, I develop new model for equilibrium sorption of metal ions on HA including splitting of hydrogen ions in chemical sorption on acidic groups. The model was proved experimentally for sorption of cupric ions. This work deals with kinetics of sorption of cobalt and nickel ions on HA to prove above mentioned new model for metal ions with lower affinity to HA.
Keywords
humic acids, sorption
Key words in English
humic acids, sorption
Authors
KLUČÁKOVÁ, M.
RIV year
2010
Released
09.09.2008
Location
Brno
ISBN
1213-7103
Periodical
CHEMICKE LISTY
Volume
102
Number
S
State
Czech Republic
Pages from
s1154
Pages to
s1155
Pages count
2
Full text in the Digital Library