Detail publikačního výsledku

Validation of SPME–GC–FID Method for Determination of Fragrance Allergens in Selected Cosmetic Products

DIVIŠOVÁ, R.; VÍTOVÁ, E.; DIVIŠ, P.; ZEMANOVÁ, J.; OMELKOVÁ, J.

Originální název

Validation of SPME–GC–FID Method for Determination of Fragrance Allergens in Selected Cosmetic Products

Anglický název

Validation of SPME–GC–FID Method for Determination of Fragrance Allergens in Selected Cosmetic Products

Druh

Článek WoS

Originální abstrakt

An analytical method for simultaneous determination of 24 legislatively restricted fragrance allergens in various cosmetic products was developed and validated using a combination of solid-phase microextraction and gas chromatography with flame ionization detector. The divinylbenzene-polydimethylsiloxane (DVB-PDMS) fiber was evaluated as the best for extraction of all studied fragrance allergens at 40oC and 20 min extraction time. All calibration curves showed good linearity in the range of 10-1 to 103 ug mL-1. Good repeatability and inter-day precision was determined for the proposed method. Detection limits for individual allergens ranged from 0.007 to 2.7 ug mL-1. The validated method was used to analyze real cosmetic samples. The obtained results indicated that not all of the analyzed cosmetic samples were labeled in accordance with European Cosmetic Directive.

Anglický abstrakt

An analytical method for simultaneous determination of 24 legislatively restricted fragrance allergens in various cosmetic products was developed and validated using a combination of solid-phase microextraction and gas chromatography with flame ionization detector. The divinylbenzene-polydimethylsiloxane (DVB-PDMS) fiber was evaluated as the best for extraction of all studied fragrance allergens at 40oC and 20 min extraction time. All calibration curves showed good linearity in the range of 10-1 to 103 ug mL-1. Good repeatability and inter-day precision was determined for the proposed method. Detection limits for individual allergens ranged from 0.007 to 2.7 ug mL-1. The validated method was used to analyze real cosmetic samples. The obtained results indicated that not all of the analyzed cosmetic samples were labeled in accordance with European Cosmetic Directive.

Klíčová slova

SPME, GC, fragrances, cosmetics

Klíčová slova v angličtině

SPME, GC, fragrances, cosmetics

Autoři

DIVIŠOVÁ, R.; VÍTOVÁ, E.; DIVIŠ, P.; ZEMANOVÁ, J.; OMELKOVÁ, J.

Rok RIV

2016

Vydáno

05.01.2015

ISSN

1233-2356

Periodikum

ACTA CHROMATOGRAPHICA

Svazek

27

Číslo

3

Stát

Polská republika

Strany od

509

Strany do

523

Strany počet

15

URL

https://akademiai.com/doi/pdf/10.1556/AChrom.27.2015.3.8

Plný text v Digitální knihovně

http://hdl.handle.net/

BibTex

@article{BUT113399,
  author="Radka {Divišová} and Eva {Vítová} and Pavel {Diviš} and Jana {Zemanová} and Jiřina {Omelková}",
  title="Validation of SPME–GC–FID Method for Determination of Fragrance Allergens in Selected Cosmetic Products",
  journal="ACTA CHROMATOGRAPHICA",
  year="2015",
  volume="27",
  number="3",
  pages="509--523",
  doi="10.1556/AChrom.27.2015.3.8",
  issn="1233-2356",
  url="https://akademiai.com/doi/pdf/10.1556/AChrom.27.2015.3.8"
}