Detail publikačního výsledku
Structural and Magnetic Properties of CoFe2-xGdxO4 (x = 0.0-0.1) Spinel Ferrite Nanoparticles synthesized by Starch-Assisted Sol-Gel Auto-combustion Method
YADAV, R.; HAVLICA, J.; KUŘITKA, I.; KOŽÁKOVÁ, Z.; BARTONÍČKOVÁ, E.; MÁSILKO, J.; KALINA, L.; WASSERBAUER, J.; HAJDÚCHOVÁ, M.; ENEV, V.
Originální název
Structural and Magnetic Properties of CoFe2-xGdxO4 (x = 0.0-0.1) Spinel Ferrite Nanoparticles synthesized by Starch-Assisted Sol-Gel Auto-combustion Method
Anglický název
Structural and Magnetic Properties of CoFe2-xGdxO4 (x = 0.0-0.1) Spinel Ferrite Nanoparticles synthesized by Starch-Assisted Sol-Gel Auto-combustion Method
Druh
Článek WoS
Originální abstrakt
In this present article, CoFe2-xGdxO4 (x = 0.0-0.1) nanoparticles were synthesized by starch-assisted sol–gel auto-combustion method. Powder X-ray diffraction patterns revealed the formation of cubic spinel ferrite with the signature of GdFeO3 phase at higher Gd3+ concentration. The field emission scanning electron microscopy study demonstrated the spherical nanoparticle in the size range 4–10 nm. Raman and Fourier transform infrared spectra supported the formation of the spinel ferrite structure in the nanocrystalline form. The X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of Co2+ and Fe3+ at the octahedral site as well as the tetrahedral site in CoFe2-xGdxO4 (x = 0.05) nanoparticles. The distribution of Fe3+ ions was obtained to be about 73 % in the octahedral sites and about 27 % in the tetrahedral sites. The distribution of Co2+ ions at the octahedral and tetrahedral sites were 78 and 22 %, respectively. The increase in saturation magnetization and coercivity from 14.59 emu/g (x = 0.00) to 16.11 emu/g (x = 0.025) and 51.75 Oe (x = 0.00) to 92.86 Oe (x = 0.050), respectively, in CoFe2-xGdxO4 nanoparticles were observed.
Anglický abstrakt
In this present article, CoFe2-xGdxO4 (x = 0.0-0.1) nanoparticles were synthesized by starch-assisted sol–gel auto-combustion method. Powder X-ray diffraction patterns revealed the formation of cubic spinel ferrite with the signature of GdFeO3 phase at higher Gd3+ concentration. The field emission scanning electron microscopy study demonstrated the spherical nanoparticle in the size range 4–10 nm. Raman and Fourier transform infrared spectra supported the formation of the spinel ferrite structure in the nanocrystalline form. The X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of Co2+ and Fe3+ at the octahedral site as well as the tetrahedral site in CoFe2-xGdxO4 (x = 0.05) nanoparticles. The distribution of Fe3+ ions was obtained to be about 73 % in the octahedral sites and about 27 % in the tetrahedral sites. The distribution of Co2+ ions at the octahedral and tetrahedral sites were 78 and 22 %, respectively. The increase in saturation magnetization and coercivity from 14.59 emu/g (x = 0.00) to 16.11 emu/g (x = 0.025) and 51.75 Oe (x = 0.00) to 92.86 Oe (x = 0.050), respectively, in CoFe2-xGdxO4 nanoparticles were observed.
Klíčová slova
Ceramic nanoparticles, Magnetic properties, Spinel ferrites
Klíčová slova v angličtině
Ceramic nanoparticles, Magnetic properties, Spinel ferrites
Autoři
YADAV, R.; HAVLICA, J.; KUŘITKA, I.; KOŽÁKOVÁ, Z.; BARTONÍČKOVÁ, E.; MÁSILKO, J.; KALINA, L.; WASSERBAUER, J.; HAJDÚCHOVÁ, M.; ENEV, V.
Rok RIV
2016
Vydáno
14.01.2015
Nakladatel
Springer
Místo
New York
ISSN
1557-1947
Periodikum
Journal of Superconductivity and Novel Magnetism
Svazek
2015
Číslo
28
Stát
Spojené státy americké
Strany od
1797
Strany do
1806
Strany počet
10
Plný text v Digitální knihovně
BibTex
@article{BUT113708,
author="Raghvendra Singh {Yadav} and Jaromír {Havlica} and Ivo {Kuřitka} and Zuzana {Kožáková} and Eva {Bartoníčková} and Jiří {Másilko} and Lukáš {Kalina} and Jaromír {Wasserbauer} and Miroslava {Mončeková} and Vojtěch {Enev}",
title="Structural and Magnetic Properties of CoFe2-xGdxO4 (x = 0.0-0.1) Spinel Ferrite Nanoparticles synthesized by Starch-Assisted Sol-Gel Auto-combustion Method",
journal="Journal of Superconductivity and Novel Magnetism",
year="2015",
volume="2015",
number="28",
pages="1797--1806",
doi="10.1007/s10948-015-2951-7",
issn="1557-1939"
}