Enhanced Charpy impact strength of epoxy resin modified with vinyl-terminated polydimethylsiloxane

Enhanced Charpy impact strength of epoxy resin modified with vinyl-terminated polydimethylsiloxane

Článek WoS

This article deals with enhancement of the toughness of epoxy resin (ER) based on diglycidyl ether bisfenol A by either polydimethylsiloxane (PDMS) or vinyl-terminated polydimethylsiloxane (VT-PDMS). To improve the compatibility of these two phases, dicumylperoxide (DCP) was used as a compatibilizer. It was established that only specific composition of the components can lead to enhancement of ER toughness without significant reduction of storage modulus, Tg, and interphase adhesion. The highest impact strength was recorded for ER with VT-PDMS (10 wt %) and DCP (2 wt %) due to increased interfacial compatibility between two phases, which was proved by 1H NMR and dielectric spectroscopy. Critical ductile brittle transition occurring between 10 and 15 wt % of rubber was observed by both morphological and dynamic mechanical analysis studies.

This article deals with enhancement of the toughness of epoxy resin (ER) based on diglycidyl ether bisfenol A by either polydimethylsiloxane (PDMS) or vinyl-terminated polydimethylsiloxane (VT-PDMS). To improve the compatibility of these two phases, dicumylperoxide (DCP) was used as a compatibilizer. It was established that only specific composition of the components can lead to enhancement of ER toughness without significant reduction of storage modulus, Tg, and interphase adhesion. The highest impact strength was recorded for ER with VT-PDMS (10 wt %) and DCP (2 wt %) due to increased interfacial compatibility between two phases, which was proved by 1H NMR and dielectric spectroscopy. Critical ductile brittle transition occurring between 10 and 15 wt % of rubber was observed by both morphological and dynamic mechanical analysis studies.

adhesives; dielectric properties; elastomers; mechanical properties; thermosets

adhesives; dielectric properties; elastomers; mechanical properties; thermosets

Jarmila Vilčáková, Lenka Kutějová, Marek Jurča, Robert Moučka, Robert Vícha, Michal Sedlačík, Adriana Kovalcik, Michal Machovský, Natalia Kazantseva

2019

15.01.2018

John Wiley & Sons, Inc.

New Jersey

1097-4628

JOURNAL OF APPLIED POLYMER SCIENCE

135

45720

Spojené státy americké

45720-01

45720-12

12

http://onlinelibrary.wiley.com/doi/10.1002/app.45720/abstract

http://hdl.handle.net/