Detail publikačního výsledku

Photophysical and Electrochemiluminescence of Coumarin-Based Oxazaborines

MIKYSEK, T.; NIKOLAOU, P.; KAFEXHOLLI, M.; ŠIMŮNEK, P.; VÁŇA, J.; MARKOVÁ, A.; VALA, M.; VALENTI, G.

Originální název

Photophysical and Electrochemiluminescence of Coumarin-Based Oxazaborines

Anglický název

Photophysical and Electrochemiluminescence of Coumarin-Based Oxazaborines

Druh

Článek WoS

Originální abstrakt

We describe the synthesis, electrochemistry, photophysics, computational analysis and electrochemiluminescence (ECL) of a new series of oxazaborine molecules. Our strategy is based on the modification of the coumarin-oxazaborine moiety to be directly joined through a carbon-carbon bond, forming donor-acceptor (D-A) chromophores. These new structures substantially change the electron distribution as well as photophysical and electrochemical behaviors with a strong effect on the final quantum yield. For all compounds, we observed a very high PL quantum yield (70-75 %) and relatively accessible first oxidation and first reduction. All of these characteristics allow us to study the ECL of these molecules, obtaining a very high ECL efficiency that is four times higher than the standard dyes, opening the application of oxazaborine as bright ECL luminophores.

Anglický abstrakt

We describe the synthesis, electrochemistry, photophysics, computational analysis and electrochemiluminescence (ECL) of a new series of oxazaborine molecules. Our strategy is based on the modification of the coumarin-oxazaborine moiety to be directly joined through a carbon-carbon bond, forming donor-acceptor (D-A) chromophores. These new structures substantially change the electron distribution as well as photophysical and electrochemical behaviors with a strong effect on the final quantum yield. For all compounds, we observed a very high PL quantum yield (70-75 %) and relatively accessible first oxidation and first reduction. All of these characteristics allow us to study the ECL of these molecules, obtaining a very high ECL efficiency that is four times higher than the standard dyes, opening the application of oxazaborine as bright ECL luminophores.

Klíčová slova

electrochemiluminescence; molecular electrochemistry; oxazaborines; donor-acceptor chromophores; coumarin

Klíčová slova v angličtině

electrochemiluminescence; molecular electrochemistry; oxazaborines; donor-acceptor chromophores; coumarin

Autoři

MIKYSEK, T.; NIKOLAOU, P.; KAFEXHOLLI, M.; ŠIMŮNEK, P.; VÁŇA, J.; MARKOVÁ, A.; VALA, M.; VALENTI, G.

Rok RIV

2021

Vydáno

15.01.2020

Nakladatel

WILEY-V C H VERLAG GMBH

Místo

WEINHEIM

ISSN

2196-0216

Periodikum

ChemElectroChem

Svazek

7

Číslo

7

Stát

Spolková republika Německo

Strany od

1550

Strany do

1557

Strany počet

8

URL

https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.201902102

BibTex

@article{BUT161646,
  author="MIKYSEK, T. and NIKOLAOU, P. and KAFEXHOLLI, M. and ŠIMŮNEK, P. and VÁŇA, J. and MARKOVÁ, A. and VALA, M. and VALENTI, G.",
  title="Photophysical and Electrochemiluminescence of Coumarin-Based Oxazaborines",
  journal="ChemElectroChem",
  year="2020",
  volume="7",
  number="7",
  pages="1550--1557",
  doi="10.1002/celc.201902102",
  issn="2196-0216",
  url="https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.201902102"
}