Detail publikačního výsledku

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

FARKA, D.; CIGÁNEK, M.; VESELÝ, D.; KALINA, L.; KRAJČOVIČ, J.

Originální název

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Anglický název

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Druh

Článek WoS

Originální abstrakt

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.

Anglický abstrakt

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.

Klíčová slova

Self-assembly; adamantane; monolayers; organic electronics

Klíčová slova v angličtině

Self-assembly; adamantane; monolayers; organic electronics

Autoři

FARKA, D.; CIGÁNEK, M.; VESELÝ, D.; KALINA, L.; KRAJČOVIČ, J.

Rok RIV

2025

Vydáno

03.09.2024

Nakladatel

AMER CHEMICAL SOC

Místo

WASHINGTON

ISSN

2470-1343

Periodikum

ACS Omega

Svazek

9

Číslo

37

Stát

Spojené státy americké

Strany od

38733

Strany do

38742

Strany počet

10

URL

https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616

Plný text v Digitální knihovně

http://hdl.handle.net/11012/250686

BibTex

@article{BUT189619,
  author="Dominik {Farka} and Martin {Cigánek} and Dominik {Veselý} and Lukáš {Kalina} and Jozef {Krajčovič}",
  title="Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers",
  journal="ACS Omega",
  year="2024",
  volume="9",
  number="37",
  pages="38733--38742",
  doi="10.1021/acsomega.4c04616",
  issn="2470-1343",
  url="https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616"
}

Dokumenty

farka-et-al-2024