Detail publikačního výsledku

Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

Originální název

Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Anglický název

Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Druh

Článek recenzovaný mimo WoS a Scopus

Originální abstrakt

Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.

Anglický abstrakt

Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.

Klíčová slova

Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins

Klíčová slova v angličtině

Nickel catalyst, living polymerization, Kinetics, Structure, Polyolefins

Autoři

Merna, J., Cihlář, J., Kučera, M., Deffieux, A., Cramail, H.

Vydáno

01.02.2005

Nakladatel

Elsevier

ISSN

0014-3057

Periodikum

EUROPEAN POLYMER JOURNAL

Svazek

2005

Číslo

41

Stát

Spojené království Velké Británie a Severního Irska

Strany od

303

Strany do

312

Strany počet

9

BibTex

@article{BUT46276,
  author="Jan {Merna} and Jaroslav {Cihlář} and Miloslav {Kučera} and Alain {Deffieux} and Henri {Cramail}",
  title="Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium",
  journal="EUROPEAN POLYMER JOURNAL",
  year="2005",
  volume="2005",
  number="41",
  pages="303--312",
  issn="0014-3057"
}