Detail publikačního výsledku

Macroscopic derivation of the kinetic mass-action law

PEKAŘ, M.

Originální název

Macroscopic derivation of the kinetic mass-action law

Anglický název

Macroscopic derivation of the kinetic mass-action law

Druh

Článek recenzovaný mimo WoS a Scopus

Originální abstrakt

Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.

Anglický abstrakt

Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.

Klíčová slova

mass action, reaction rate, thermodynamic polynomial, thermodynamics

Klíčová slova v angličtině

mass action, reaction rate, thermodynamic polynomial, thermodynamics

Autoři

PEKAŘ, M.

Rok RIV

2010

Vydáno

01.01.2010

Nakladatel

Springer-Verlag

ISSN

1878-5190

Periodikum

Reaction Kinetics Mechanisms and Catalysis

Svazek

99

Číslo

1

Stát

Maďarsko

Strany od

29

Strany do

35

Strany počet

7

URL

http://link.springer.com/10.1007/s11144-009-0101-6

Plný text v Digitální knihovně

http://hdl.handle.net/11012/19701

BibTex

@article{BUT48539,
  author="Miloslav {Pekař}",
  title="Macroscopic derivation of the kinetic mass-action law",
  journal="Reaction Kinetics Mechanisms and Catalysis",
  year="2010",
  volume="99",
  number="1",
  pages="29--35",
  doi="10.1007/s11144-009-0101-6",
  issn="1878-5190",
  url="http://link.springer.com/10.1007/s11144-009-0101-6"
}

Dokumenty

Macroscopic derivation of the kinetic mass-action law