Detail publikačního výsledku
Plasma polymer films of tetravinylsilane modified by UV irradiation
ČECH, V.; KONTÁROVÁ, S.; TRIVEDI, R.; PEŘINA, V.; ZEMEK, J.; MIKULÍK, P.; CAHA, O.
Originální název
Plasma polymer films of tetravinylsilane modified by UV irradiation
Anglický název
Plasma polymer films of tetravinylsilane modified by UV irradiation
Druh
Abstrakt
Originální abstrakt
As-deposited plasma polymer films of tetravinylsilane were modified by UV irradiation at ambient conditions. Surface and bulk spectroscopic techniques confirmed significant changes in chemical composition and structure that resulted in increased mechanical constants (Young's modulus, hardness) and density of the material due to the formation of a stronger polymer network with higher cross-linking. A decrease of the refractive index and extinction coefficient of the UV-irradiated material was caused by UV-induced chain scission and subsequent oxidation of the plasma polymer network. The surface morphology (RMS roughness) and wettability (surface free energy) of films can be controlled by UV exposition time. The most intensive aging effect was observed for the as-deposited film; in contrast, the 1000-min-UV-irradiated film appeared stable over 134 days. UV treatment can be characterized as an effective tool for additional tailoring of plasma polymer films according to their applications.
Anglický abstrakt
As-deposited plasma polymer films of tetravinylsilane were modified by UV irradiation at ambient conditions. Surface and bulk spectroscopic techniques confirmed significant changes in chemical composition and structure that resulted in increased mechanical constants (Young's modulus, hardness) and density of the material due to the formation of a stronger polymer network with higher cross-linking. A decrease of the refractive index and extinction coefficient of the UV-irradiated material was caused by UV-induced chain scission and subsequent oxidation of the plasma polymer network. The surface morphology (RMS roughness) and wettability (surface free energy) of films can be controlled by UV exposition time. The most intensive aging effect was observed for the as-deposited film; in contrast, the 1000-min-UV-irradiated film appeared stable over 134 days. UV treatment can be characterized as an effective tool for additional tailoring of plasma polymer films according to their applications.
Klíčová slova
Thin film; PECVD; tetravinylsilane; UV irradiation
Klíčová slova v angličtině
Thin film; PECVD; tetravinylsilane; UV irradiation
Autoři
ČECH, V.; KONTÁROVÁ, S.; TRIVEDI, R.; PEŘINA, V.; ZEMEK, J.; MIKULÍK, P.; CAHA, O.
Rok RIV
2010
Vydáno
22.12.2009
Kniha
Book of Abstracts, 7th AEPSE 2009, Busan
Strany od
1
Strany do
1
Strany počet
1
BibTex
@misc{BUT60919,
author="Vladimír {Čech} and Soňa {Kontárová} and Rutul Rajendra {Trivedi} and Vratislav {Peřina} and Josef {Zemek} and Petr {Mikulík} and Ondřej {Caha}",
title="Plasma polymer films of tetravinylsilane modified by UV irradiation",
booktitle="Book of Abstracts, 7th AEPSE 2009, Busan",
year="2009",
pages="1--1",
note="Abstract"
}